Résumé Thermochimie SMP1 SMC1 PDF

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Résumé Thermochimie SMP1 SMC1 PDF

La thermodynamique est la science des échanges d'énergie entre les systèmes, ou entre les systèmes et le milieu extérieur, lors de transformations de la matière. Elle ne s'intéresse pas aux mécanismes réactionnels élémentaires qui président à ces transformations, ni à la vitesse à laquelle les systèmes évoluent. Tous les processus naturels sont soumis aux lois fondamentales de la thermodynamique. Dans les cas simples ces lois peuvent permettre de prévoir le bilan énergétique d'une transformation (objet du cours de thermochimie de cette année) et également le sens de l'évolution d'un système (objet du cours de thermodynamique chimique de seconde année). Le terme thermodynamique est introduit en 1849 par William Thomson, futur Lord Kelvin. On peut situer la « génèse » de la thermodynamique aux années 1820-1865, riches des travaux de Carnot, Mayer, Joule, Thomson, Helmholtz, ou encore Clausius.

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